Selenophosphate

In this article we will analyze the impact of Selenophosphate on contemporary society. Selenophosphate has been the subject of debate and study for years, and its influence resonates in all areas of modern life. Through a multidisciplinary approach, we will examine the different facets of Selenophosphate and its relevance today. From its impact on popular culture to its implications on the global economy, Selenophosphate continues to be a topic of interest to academics, experts, and the general public. Throughout this article, we will explore the implications and challenges that Selenophosphate poses in today's world, providing new perspectives and reflections on this phenomenon.

A selenophosphate is a chemical compound containing phosphate anions substituted with selenium. Over 7000 compounds are known with a bond between selenium and phosphorus. Compared to phosphorus-sulfur compounds selenophosphates are less thermally stable, and more easily destroyed by water. However they are more stable than tellurophosphates which have an even weaker phosphorus-tellurium bond.[1] Selenophosphates have an oxidation number for phosphorus of +5. But in many there are bonds between phosphorus atoms, reducing the oxidation state to +4, Some may be termed selenophosphites.[2]


Different structural anions include hexaselenohypodiphosphate 4− and 4− with decalin structure and 2− with dicyclobutane structure.[1]

Selenophosphates are coloured, often orange. They are semiconductors.

The first selenodiphosphate was discovered in 1973 by H. Hahn.[3]

Selenophosphate compounds may have some or all of the selenium replaced by sulfur.[4]

Formation

Selenophosphates can be produced by melting phosphorus selenide with metal selenides.

Molecular biology

Selenocysteine is produced in many organisms from a selenophosphate. In humans and other eucaryotes, this is facilitated by the enzyme selenophosphate synthetase 1. Selenium is connected to phosphorus using a reaction with selenide and adenosine triphosphate[5]

List

formula name mw crystal system space group unit cell Å volume density comments references
4·2py water stable [6]
(NH4)4(P2Se6)(H2O)2 triclinic P1 a=7.3306 b=7.3761 c=9.5501 α =70.405° β =74.109° γ =60.681° Z=1 420.37 2.544 [7]
4·H2O water stable [6]
(NBu4)2P2Se8 bis(Tetrabutylammonium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide acetonitrile solvate monoclinic P21/c a 9.6284 b 16.9553 c 16.0899 β 96.875° chair config [8]
(NBu4)3P9Se14 orange-red [9]
bis(1-Butyl-3-methylimidazolium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide monoclinic P21/n a =7.6642 b =10.9948 c =17.0380 β =91.211° chair config [8]
bis(tetrakis(Acetonitrile-N)-lithium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide orthorhombic Pbam a 20.0535(6)Å b 12.1200(5)Å c 15.0831 cradle config [8]
bis((Tetrapyridine)-lithium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide triclinic P1 a 10.1582 b 10.7716 c 12.750 α 95.271° β 94.847° γ 114.219° cradle config [8]
Na2P4Se2 red-brown; P4 bicyclo structure [10]
Na3PSe4 cubic I43m a=7.3094 Z=2 3.53 Na ion conductor 1 mS cm−1 [11]
Na4P2Se6 orthorhombic Cmca a = 11.836 b = 13.311 c = 8.061 Z = 4 1270.0 3.283 [12]
Na4(P2Se6)(H2O)6 monoclinic P21/c a 26.0636 b 7.2350 c 20.7197 β 113.387° Z=8 3586.13 2.726 [7]
Mg2P2Se6 R3 a = 6.404 c = 20.194 Z=3 [13]
KPSe6 orthorhombic Pca21 a = 11.49 b = 6.791 c = 11.29 Z = 4 orange; NLO χ(2)≈142.8 pm V−1; band gap 2.1 eV [14][15][16][17]
K4Sc2(PSe4)2(P2Se6) monoclinic C2/c a=22.668Å b=6.8147Å c=19.828 β=113.91° [18]
K2P2Se6 trigonal P3121 a = 7.2728, c = 18.872 Z = 3 at 298 K; SHG 50× AgGaSe2 [19]
K2P2Se6 trigonal P3121 a = 14.4916 c = 18.7999 Z = 12 at 173 K [19]
K3PSe4·2Se6 cubic Fd3 a = 16.415 at 193 K [20]
K4(P2Se6)(H2O)4 orthorhombic Cmca a =11.921 b =12.46 c =11.752 Z=4 1745.6 2.908 [7]
K6P8Se18 1903.66 monoclinic P21/n a=9.746 b=8.332 c=23.054 β=90.54° Z=2 1872.1 3.377 orange [21]
Ca2P2Se6 monoclinic P21/n a = 9.664 b = 7.519 c = 6.859 β = 92.02° [22]
K4Sc2(PSe4)2(P2Se6) 737.82 monoclinic C2/c a=22.668 b=6.815 c=19.828 β =113.91° Z=8 2800.2 3.500 orange-yellow; turns red in air; band gap 2.25 eV [23]
KTiPSe5 [24]
K4Ti2(P2Se9)2(P2Se7) black [24]
Cr2P2Se6 [25]
LiCrP2Se6 [26]
MnPSe3 trigonal R3 band gap 2.5 eV [27][28]
K2MnP2Se6 monoclinic P21/n a=6.5349 b=12.696 c=7.589 β=102.67° Z=2 614.3 [29]
FePSe3 [27]
Fe2P2Se6 trigonal R3 band gap 1.3 eV [13][28]
K2FeP2Se6 monoclinic P21/n a=6.421 b=12.720 c=7.535 β=102.58 Z=2 600.7 red [29]
CuP2Se 2D semiconductor; metallises under pressure [30]
m-Cu4P2Se6 monoclinic P21/c a 6.370 b 11.780 c 20.013 β 90.03° [31]
Cu3PSe4 orthorhombic Pmn21 a=7.700 b=6.677 c=6.385 328.3 [32]
t-Cu4P2Se6 triclinic P1 a 7.104 b 11.889 c 12.759 α 74.35° β 79.63° γ 80.85° [31]
Cu4P3Se4 triclinic P1 a 6.440 b 7.085 c 10.616 α 73.11° β 74.86° γ 77.00° [31]
Cu4P4Se3 monoclinic P21/c a 16.446 b 6.515 c 17.339 β 119.08° [31]
CuP2Se orthorhombic Pbca a 5.608 b 6.496 c 16.570 [31]
CuAl trigonal R3 a = 6.2795 c = 19.9713 Z =3 [33]
K2Cu2P4Se10 1118.78 monoclinic P21/n a=10.627 b=7.767 c=11.966 β=109.125° Z=2 933.2 3.981 red [34]
K3Cu3P3Se9 monoclinic P21/c a = 8.741 b = 10.774, c = 20.033, β = 92.96° [35][36]
Et=Ethyl; diethyl diselenophosphate hexaselenodiphosphate(IV) [37]
iPr=isopropyl [37]
CuCr monoclinic C2/m a=6.193 b=10.724 c=6.909 β=107.2° Z=2 690.2 4.9 melt 730 °C; dark red [3]
Zn2P2Se6 R3 a = 6.290 c = 19.93 Z=3 [13]
K2ZnP2Se6 monoclinic P21/c a = 12.537 b = 7.274 c = 14.164 β = 109.63° Z = 4 1216 yellow [38][39]
LiGaP2Se6 [26]
K4GeP4Se12 orthorhombic Pca21 a=13.9465 b=7.2435 c=24.0511 [40]
K4Ge4-xPxSe12 monoclinic P21/c a = 6.7388 b = 13.489 c = 6.3904 β = 91.025° [41]
K7As3(P2Se6)4 monoclinic P21/c a=25.0706 b=9.5948 c=59.6227 β=93.384° melt 388 °C [42]
K6As2(P2Se6)3 monoclinic P21/c a 8.0898 b 23.3142 c 12.1919 β 124.809° melt 410 °C; orange; band gap 2.2 eV [42]
RbPSe6 orthorhombic Pca21 a = 11.776 b = 6.858 c = 11.460 Z = 4 NLO χ(2)≈150 pm V−1 [15][16]
Rb2P2Se6 trigonal P3121 a = 7.2982 c = 19.002 and Z = 3 100 K [19]
Rb4P2Se9 monoclinic C2/c a = 9.725 b = 10.468 c = 19.155 β = 93.627° Z = 4 1946.1 3.804 [12]
Rb4P6Se12 orthorhombic Pca21 a =16.409 b =10.64 c =15.105 bicyclic with >PP< bridge and -SePSe2PSe2Se- ring [43]
Rb10P4Se25 [44]
Rb4(P2Se6)(H2O)4 orthorhombic Pnnm a 9.834 b 12.456 c 7.585 Z=2 929.1 3.395 [7]
RbTiPSe5 [24]
Rb4Ti2(P2Se9)2(P2Se7) orthorhombic Fdd2 a=35.55 b=37.315 c=6.574 Z=4 8772 3.956 black [24][45]
Rb2MnP2Se6 [29]
Rb2ZnP2Se6 triclinic P1 a = 7.494 b = 7.601 c = 12.729 α = 96.57° β = 105.52° γ = 110.54° Z = 2 636.6 [39]
Rb4GeP4Se12 orthorhombic Pca21 a=14.1881 b=7.3566 c=24.2914 [40]
Rb6Ge2P2Se14 triclinic P1 a = 7.2463 b = 9.707 c = 11.987 α = 79.516° β = 89.524° γ = 68.281° band gap 2.2 eV [41]
Sr2P2Se6 monoclinic P21/n a = 9.844 b = 7.788 c = 6.963 β = 91.50° Z=2 [22]
NaYP2Se6 647.6 triclinic P1 a=6.9456 b=7.4085 c=9.5306 α=88.819° β=87.748° γ=89.580° Z=2 yellow [46][47] follow up refs
KYP2Se6 orthorhombic P212121 a = 6.7366 b = 7.4286 c = 21.603 Z = 4 [46][48]
Cp′′ = C5H3tBu2 1269.41 monoclinic P21/n a=15.2831 b=9.91947 c=18.6250 β=102.835° Z=2 2753 1.531 dark purple [49]
KZrPSe6 orthorhombic Pmc21 a=3.7079 b=15.074 c=18.491 [50]
RbZrPSe6 [50]
KNb2PSe10 monoclinic Pc a=7.2931 b=15.612 c=13.557 β=106.64° resistivity 4.5 Ω·cm [51]
RbNb2PSe10 monoclinic Pc a=7.381 b=7.8359 c=13.564 β=106.75° [51]
K3RuP5Se10 monoclinic P21/m a 11.2099 b 7.2868 c 12.3474 β 93.958° [52]
PdPSe semiconductor [53]
K2PdP2Se6 [24]
Rb2PdP2Se6 [24]
Ag4P2Se6 1013.69 orthorhombic P212121 a=6.5760 b=11.5819 c=14.137 Z=4 1076.8 5.966 melt 642 °C; dark red [54]
AgAl monoclinic C2/m a=6.348 b=10.989 c=7.028 β=107.2° Z=2 melt 588 °C; yellow [3]
K2Ag2P2Se6 monoclinic P21/c a=8.528 b=11.251 c=20.975 β=93.24° Z=4 2009 orange [29]
AgCrP2Se6 monoclinic C2/m a=6.305 b=10.917; c=6.991 β=107.7° Z=2 melt 720 °C; dark red [3]
AgCrP2Se6 P3112 a=6.3257 c=20.0198 layered; antiferromagnetic <42K; band gap 1.240 eV [55]
AgGa orthorhombic Pbca α=12.169 b=22.484 c=7.473 Z=4 2044.7 melt 450 °C; orange [3]
AgGa trigonal P31/c a=6.375 c=13.320 Z=2 468.81 5.05 dark red [3]
AgScP2Se6 688.54 trigonal P31/c a=6.463 c=13.249 Z=2 482.93 4.735 orange or brown [56]
CdPSe3 [27]
K2CdP2Se6 monoclinic P21/n dark yellow [38]
Rb2CdP2Se6 819.05 monoclinic P21/n a=6.640 b=12.729 c=7.778 β=98.24° Z=2 650.5 4.180 dark yellow; air stable [38]
Rb8Cd4(Se2)(PSe4)4 [24]
InPSe3 [27]
In2(P3Se9) monoclinic P21/n [35]
LiInP2Se6 657.46 trigonal P31/c a=6.397 c=13.350 Z=2 473.15 4.615 band gap 2.06 eV [57]
(Ph4P) monoclinic C2/c a = 23.127 b = 6.564 c = 19.083 β = 97.42° Z = 4 2873 @23 °C yellow [58]
KInP2Se6 monoclinic P21/n a=7.511 b=6.4861 c=22.789 β=98.91° Z=4 1096.9 [59]
K5In3(μ3-Se)(P2Se6)3 triclinic P1 a 7.6603 b 13.1854 c 18.378 α 87.04° β 88.659° γ 82.025° [60]
K4In4(μ-Se)2(P2Se6)3 monoclinic P21/c a 19.707 b 7.712 c 13.229 α 90° β 106.42° [60]
K4In2(PSe5)2(P2Se6) monoclinic Cc a=11.1564 b=22.8771 c=12.6525 β=109.039° Z=4 brick-red; air stable [61]
K4In4(μ-Se)(P2S2.36Se3.64)3 triclinic P1 a 7.7709 b 13.0007 c 18.9382 α 105.382° β 92.632° γ 91.91° [60]
CuInP2Se6 trigonal P31/c a=6.392 c=13.338 Z=2 472.0 5.0 melt 642 °C; dark red [3]
AgInP2Se6 trigonal P31/c a=6.483 c=13.330 Z=2 485.2 5.2 semiconductor; melt 673 °C; dark red; band gap 1.79 eV [62][3]
SnP2Se6 R3 a = 6.3213 c = 19.962 band gap 1.36–1.41 eV [63]
Sn2P2Se6 [64]
Na11.1Sn2.1P0.9Se12 tetragonal I41/acd a=14.2446 c=28.473 Z=8 5777.4 3.403 Na+ ion conductivity 3.0 mS/cm [65]
Rb3Sn(PSe5)(P2Se6) monoclinic P21/a a=14.013 b=7.3436 c=21.983 β=106.61° Z=4 black [61]
K10Sn3(P2Se6)4 trigonal R3 a = 24.1184 c = 7.6482 @100K; band gap 1.82 eV [66]
Rb4Sn5P4Se20 2638.41 trigonal P3m1 a=7.6163 c=18.6898 Z=1 938.91 4.64 black [67]
Rb4Sn2Ag4(P2Se6)2 monoclinic P21/n a=11.189 b=7.688 c=21.850 β=94.31° Z=2 1874.2 4.639 black [24][68]
Rb5 triclinic P1 a 11.745 b 19.23 c 7.278 α 99.97° β 107.03° γ 87.16° [69]
Sb4(P2Se6)3 monoclinic P21/n a = 20.777 b = 7.4935 c = 9.4949 β = 91.25° [70]
KSbP2Se6 696.55 [35]
β-KSbP2Se6 696.55 monoclinic P21 a=6.8925 b=7.8523 c=10.166 β=91.487 Z=2 550.4 4.203 dark red [71]
AgSbP2Se6 hygroscopic [72]
α-CsPSe6 monoclinic P21/n a = 6.877 b = 12.713 c = 11.242 β = 92.735° Z = 4 orange [14][15]
β-CsPSe6 637.64 tetragonal P421c a = 12.526 c = 12.781 Z = 8 2005.3 4.224 red orange; metastable; SHG χ(2) ~30 pm/V [14]
Cs2P2Se8 orthorhombic Ccce a = 14.982 b = 24.579 c = 13.065 band gap 2.44 ± 0.2 eV; P2Se4 ring; third harmonic generator coefficient 2.4 ± 0.1 × 105 pm2/V2 [73]
Cs3PSe4 orthorhombic Pnma a = 10.0146 b = 11.990 c = 9.9286 Z = 4 1192.2 4.154 [12]
Cs4P2Se9 [24]
Cs4P2Se10 triclinic P1 a=7.359 b=7.455 c=10.142 α=85.938°, β=88.055° γ=85.609° 4− [74]
Cs4 1664.98 monoclinic P21/n a =10.836 b =10.5437 c =12.273 β =98.661° 1386.3 3.989 orange; melt 697; NLO [75]
Cs5 1766.92 tetragonal P4 a =13.968 c =7.546 Z=2 1472.2 3.986 orange; NLO; band gap 2.17 eV [75][76]
Cs10P8Se20 orthorhombic Pnnm a = 26.5456 b = 8.0254 c = 11.9031 Z = 2 2535.8 4.133 (PSe2)3Se rings and P2Se6 [77]
Cs4(P2Se6)(H2O)4 orthorhombic Pnnm a=10.0514 b=12.6867 c=7.8403 Z=2 999.8 3.775 [7]
K0.6Cs0.4PSe6 orthorhombic Pca21 a=11.830 b=6.908 c=11.516 Z=4 941.1 4.085 orange; band gap 2.1 eV; SHG χ(2) ~150 pm/V [14]
KCsP2Se8 orthorhombic Ccce a = 14.782 b = 23.954 c = 13.044 band gap 2.36 ± 0.2 eV [73]
Cs2MnP2Se6 monoclinic P21/n 6.4761 b=13.006 c=7.974 β=93.09° Z=2 670.6 [29]
Cs2FeP2Se6 [29]
Cs2Cu2P2Se6 monoclinic P21/c a=9.958 b=13.067 c=10.720 β=102.46° Z=4 1363 dark green [29]
Cs2ZnP2Se6 triclinic P1 a = 7.6543 b = 7.7006 c = 12.737 α = 97.007° β = 104.335° γ = 109.241° Z = 2 669.5 yellow; band gap 2.67 eV [39][76]
Cs4GeP4Se12 orthorhombic Pca21 a=14.3268 b=7.6202 c=24.6301 [40]
Cs6As2(P2Se6)3 monoclinic P21/c a=19.5759 b=7.9206 c=13.0553 β=101.914° orange band gap 2.1 eV [42]
Cs5As(P2Se6)2 tetragonal P42/m a=13.826 c=7.5173 melt 416 °C; red; band gap 2.0 eV [42]
RbCsP2Se8 orthorhombic Ccce band gap 2.41 ± 0.2 eV [73]
CsZrPSe6 band gap 2.0 eV [76][50]
CsNb2PSe10 monoclinic Pc a=14.6257 b=7.8097 c=13.5533 β=98.557° [51]
Cs4Pd(PSe4)2 monoclinic P21/c a = 7.491 b = 13.340 c = 10.030 β = 92.21° Z = 2 red [78]
Cs10Pd(PSe4)4 tetragonal P42c a = 13.949 c = 11.527 Z = 4 red [78]
Cs2PdP2Se6 tetragonal P42/mnm a = 8.5337 c = 10.5595 Z = 4 black [78]
Cs2Ag2P2Se6 monoclinic P21/n a=6.807 b=12.517 c=8.462 β=95.75° Z=2 717.3 yellow [29]
Cs2CdP2Se6 monoclinic P21/n yellow [38]
Cs5In(P2Se6)2 tetragonal P42/m a = 13.886 c = 7.597 Z = 2 1464.9 @23 °C; dark orange [58]
Cs4Sn(P2Se6)2 1721.73 trigonal R3 a=7.808 c=37.905 Z=3 2001.4 4.285 black [79]
α-Cs2SnP2Se6 920.2 monoclinic P21/c a=10.230 b =12.990 c=10.949 β=94.529° 1450.5 4.2126 orange [79]
Cs2SnP2Se6 monoclinic P21/c a = 10.1160 b = 12.7867 c = 11.0828 β = 94.463° @100K [66]
Cs4(Sn3Se8)2 2828.17 tyrigonal P3m1 a=7.695 c=18.797 Z=1 964.0 4.872 black; 2D [79]
Cs6 triclinic P1 a 9.899 b 12.416 c 7.497 α 91.62° β 110.19° γ 79.94° [69]
CuSbP2Se6 C2/m [80]
AgSbP2Se6 C2/m [80]
Cs8Sb4(P2Se6)5 [35]
Ba2P2Se6 monoclinic P21/n a = 10.355 b = 7.862 c = 7.046 β = 90.83° Z=2 [22]
Ba3(PSe4)2 monoclinic P21/a a = 12.282 b = 6.906 c = 18.061 β = 90.23° Z = 4 [81][82]
Ba3PO4PSe4 triclinic P1 a=6.779 b=7.108 c=12.727 α=82.45 β=78.88 γ=81.34 Z=2 orange [81]
KBaPSe4 orthorhombic Pnma a=11.972 b=6.973 c=10.388 Z=4 pale orange [81]
KLaP2Se6 713.71 monoclinic P21/c a=12.425 b=7.8047 c=11.9279 β=109.612° 1089.6 4.351 yellow [35]
K2La(P2Se6)1/2(PSe4) monoclinic P21/n a = 9.4269 b = 7.2054 c = 21.0276 β = 97.484° Z = 4 [83]
K3La(PSe4)2 monoclinic P21/c a = 9.5782 b = 17.6623 c = 9.9869 β = 90.120° Z = 4 [83]
K3LaP2Se8 [84]
K4La0.67(PSe4)2 orthorhombic Ibam a = 19.0962 b = 9.1408 c = 10.2588 Z = 4 [83]
K6LaP4Se16
K8.5La1+1/3(PSe4)4 orthorhombic Ccca a = 18.2133 b = 38.0914 c = 10.2665 Z = 8 [83]
Ce4(P2Se6)3 722.06 monoclinic P21/c a = 6.8057 b = 22.969 c = 11.7226 β = 124.096° Z = 6 4.741 orange [85]
NaCeP2Se6 monoclinic P21/c a = 12.1422 b = 7.6982 c = 11.7399 β = 111.545° Z=4 yellow [85]
KCeP2Se6 monoclinic P21/c [46]
Cu0.4Ce1.2P2Se6 monoclinic P21/c a = 12.040 b = 7.6418 c = 11.700 β = 111.269° Z = 4 yellow [85]
Rb2CeP2Se7 monoclinic P21/n red; air sensitive [86]
Rb3CeP2Se8 1090.13 monoclinic P21/c a = 9.6013 b = 18.0604 c = 10.0931 β = 90.619° Z = 4 1750.07 4.137 orange; air sensitive [86]
Rb9Ce(PSe4)4 monoclinic C2/c a=21.446 b=10.575 c=18.784 β =115.94° Z=4 3831 3.980 orange; air and water destroyed; soluble in 18-crown-6 + dmf; band gap 2.26 eV [44]
AgCeP2Se6 monoclinic P21/c a = 9.971 b = 7.482 c = 11.757 β = 145.630° Z=2 orange [85]
CsCe monoclinic P21/c a = 12.9786 b = 7.7624 c = 11.9843 β = 106.589° Z = 4 [87]
KPrP2Se6 monoclinic P21/c [46]
Cs2PrP2Se7 monoclinic P21/n a=10.2118 b=7.2423 c=20.3741 β =98.624° Z=4 [88]
Eu2P2Se6 monoclinic P21/n a = 9.779 b = 7.793 c = 6.957 β = 91.29° Z=2 [22]
LiEuPSe4 orthorhombic Ama2 a = 10.5592 b = 10.415 c = 6.4924 Z = 4 red; air unstable [89]
Na8Eu2(Si2Se6)2 monoclinic C2/m a=7.090 b=12.228 c=7.950 β=107.427° Z = 1 657.6 [90]
KEuPSe4 monoclinic P21/m a = 6.8469 b = 6.9521 c = 9.0436 β = 107.677° Z = 2 red; air unstable [89]
KEuPSe4 orthorhombic Pnma a = 17.516 b = 7.0126 c = 6.9015 Z = 4 [83]
K4Eu(PSe4)2 orthorhombic Ibam a = 19.020 b = 9.131 c = 10.198 Z = 4 [35][91]
Cs3GdP2Se8 monoclinic P21/c [86]
NaSmP2Se6 709.94 triclinic P1 a 6.8368 b 7.5312 c 9.557 α 90.799° β 91.910° γ 90.351° Z=2 red [46]
Na9Sm(Ge2Se6)2 monoclinic C2/m a = 7.916 b = 12.244 c = 7.105 β = 106.99° Z = 1 658.6 [90]
KSmP2Se6 725.15 monoclinic P21 a=6.7888 b=7.6185 c=10.1962 β=91.508 Z=2 527.17 4.568 red [92]
CsSmP2Se6 orthorhombic P212121 a = 6.8867 b = 7.5448 c = 22.152 Z = 4 [46][87]
NaGdP2Se6 715.94 triclinic P1 a 6.8464 b 7.4916 c 9.5372 α 90.813° β 92.026° γ 90.241° Z=2 yellow [46]
KGdP2Se6 monoclinic P21 a=6.7802 b=7.5809 c=10.1967 β=91.638 Z=2 523.97 4.640 yellow [46][92]
Rb2GdP2Se7 1037.73 monoclinic P21/n a = 10.137 b = 7.212 c = 20.299 β = 98.23° Z = 4 1468.8 4.692 orange; air sensitive [86]
NaTbP2Se6 717.61 triclinic P1 a 6.8854 b 7.4580 c 9.5196 α 89.068° β 87.899° γ 89.974° Z=2 yellow [46]
KTbP2Se6 monoclinic P21 a=6.7609 b=7.5570 c=10.2158 β=91.732 Z=2 521.71 4.671 yellow [46][92]
KTbP2Se6 orthorhombic red over 9.2 GPa [93]
NaDyP2Se6 721.19 triclinic P1 a 6.9114 b 7.4258 c 9.5256 α 88.914° β 87.829° γ 89.695° Z=2 yellow [46]
CsEr monoclinic P21/c a = 7.5381 b = 12.8192 c = 12.7647 β = 106.898° Z = 4 [87]
AgErP2Se6 810.83 trigonal P31/c a=6.578 c=13.410 Z=2 502.6 5.358 dark brown [56]
AgTmP2Se6 812.50 trigonal P31/c a=6.567 c=13.422 Z=2 501.27 5.383 dark brown [56]
K3AuP2Se8 monoclinic Cc a = 7.122 b = 12.527 c = 18.666 β = 96.06° Z = 4 [94]
Rb3AuP2Se8 monoclinic Cc [94]
Cs3AuP2Se8 monoclinic Cc [94]
K2Au2P2Se6 monoclinic C2/m a = 12.289 b = 7.210 c = 8.107 β = 115.13° Z = 2 black [94]
Rb2Au2P2Se6 monoclinic C2/m [94]
Rb2Au2P2Se6 monoclinic P21/n a=11.961 b=10.069 c=32.137 β=91.37° Z=12 3869 4.653 @-120 °C black [95]
Hg2P2Se6 [35][96]
K2HgP2Se6 monoclinic P21/c a=13.031 b=7.308 c=14.167 β=110.63° Z=4 1262.6 4.285 dark yellow [38]
Rb2HgP2Se6 monoclinic P21/c drak yellow [38]
Rb8Hg4(Se2)(PSe4)4 P42/n a=17.654 c=7.226 [24][97]
Tl4P2Se6 trigonal R3 a=6.3808 c= 20.014 melt 963 K [35][98]
TlInP2Se6 triclinic P1 a=6.4488 b=7.5420 c=12.166 α=100.72° β=93.63° γ=113.32° melt 875K [99][98]
TlSbP2Se6 monoclinic P21 a = 6.843 b = 7.841 c = 9.985 β = 90.77° Z = 2 melt 720K; band gap 1.75 eV [100]
Pb2P2Se6 monoclinic Pn a = 9.742 b = 7.662 c = 6.898 β=91.44° Z=2 514.73 6.13 melt 812 °C;band gap 1.88 eV [35][101][102]
Na1.5Pb0.75PSe4 cubic I43d a=14.3479 Z=16 band gap 2 eV [103]
RbPbPSe4 red water stable [91]
Rb4Pb(PSe4)2 orthorhombic Ibam a = 19.134 b = 9.369 c = 10.488 Z = 4 orange water unstable [91]
CsPbPSe4 orthorhombic Pnma a = 18.607 b = 7.096 c = 6.612 Z = 4 red water stable [91]
Cs4Pb(PSe4)2 orange water unstable [91]
Bi4(P2Se6)3 monoclinic P21/n a = 20.869 b = 7.4745 c = 9.5923 β = 91.73° [70]
β-Bi4(P2Se6)3 triclinic P1 a = 12.2303 b = 6.7640 c = 17.866 α = 90.493° β = 94.133° γ = 91.163° black [104]
KBiP2Se6 783.78 monoclinic P21 a 6.9183 b 7.663 c 10.239 β 91.508° Z=2 542.6 4.797 [35][71]
CuBiP2Se6 R3 a = 6.553 c = 39.76 lamellar; p-type semiconductor; work function 5.26 eV [105][106]
AgBiP2Se6 R3 a = 6.652 c = 39.61 lamellar [105]
Cs5BiP4Se12 orthorhombic Pmc21 a = 7.5357 b = 13.7783 c = 28.0807 Z = 4 band gap 1.85 eV; melt 590 °C [107]
α-TlBiP2Se6 monoclinic P2l/c a =12.539 b =7.499 c =12.248 β =113.731° chains; band gap 1.23,1eV [108]
β-TlBiP2Se6 monoclinic P2l/c a =12.25 b =7.5518 c =22.834 β =97.65° melt 544 °C; layers; band gap 1.27 eV [108]
K2ThP3Se9 triclinic P1 a = 10.4582 b = 16.5384 c = 10.2245 α = 107.637 β = 91.652 γ = 90.343° Z = 2 [109]
β-K2ThP3Se9 monoclinic P21/n a = 10.2697 b = 7.7765 c = 20.472 β = 92.877° Z = 4 yellow [110]
Rb2ThP3Se9 triclinic P1 a = 10.5369 b = 16.6914, c = 10.2864 α = 107.614° β = 92.059° γ = 90.409° Z = 2 [109]
Rb7Th2P6Se21 triclinic P1 a = 11.531 b = 12.359 c = 16.161 α = 87.289° β = 75.903° γ = 88.041° Z = 2 red; band gap 2.0 eV [111]
Cs4Th4P4Se26 orthorhombic Pbca a = 12.0130 b = 14.5747 c = 27.134 Z = 8 orange; (P2Se9)6- anion [112]
Cs4Th2P5Se17 monoclinic P2l/c a = 10.238 b = 32.182 c = 10.749 β = 95.832° Z = 4 [109]
K2UP3Se9 triclinic P1 a = 10.407( b = 16.491 c = 10.143 α= 107.51° β = 91.74° γ = 90.28° Z = 4 black [24][113]
Rb4U2P5Se17 triclinic P1 a =10.0824 b = 10.6905 c = 15.7845 α = 84.678 β = 76.125 γ = 85.874° @100K [114]
Rb4U4P4Se26 3470.84 orthorhombic Pbca a=11.9779 b=14.4874 c=27.1377 Z=4 4709.17 4.895 U5+ [115]
Cs2U2(P2Se9)(Se2)2 orthorhombic Pbca a 11.769 b 14.389 c 26.537 black [116]


References

  1. ^ a b Devillanova, Francesco A.; Mont, Wolf-Walther Du (2013). "Chalcogen-Phosphorus (and Heavier Congener) Compounds". Handbook of Chalcogen Chemistry: New Perspectives in Sulfur, Selenium and Tellurium. Royal Society of Chemistry. p. 238. ISBN 978-1-84973-623-7.
  2. ^ Sanna, Michela; Ng, Siowwoon; Pumera, Martin (August 2021). "Layered transition metal selenophosphites for visible light photoelectrochemical production of hydrogen". Electrochemistry Communications. 129: 107077. doi:10.1016/j.elecom.2021.107077. hdl:11012/203046.
  3. ^ a b c d e f g h Pfeiff, Regine; Kniep, Rüdiger (July 1992). "Quaternary selenodiphosphates(IV): MIMIII, (MI =Cu, Ag; MIII = Cr, Al, Ga, In)". Journal of Alloys and Compounds. 186 (1): 111–133. doi:10.1016/0925-8388(92)90626-K.
  4. ^ Krauskopf, Thorben; Pompe, Constantin; Kraft, Marvin A.; Zeier, Wolfgang G. (24 October 2017). "Influence of Lattice Dynamics on Na + Transport in the Solid Electrolyte Na 3 PS 4– x Se x". Chemistry of Materials. 29 (20): 8859–8869. doi:10.1021/acs.chemmater.7b03474.
  5. ^ Tamura, Takashi; Yamamoto, Shinpei; Takahata, Muneaki; Sakaguchi, Hiromich; Tanaka, Hidehiko; Stadtman, Thressa C.; Inagaki, Kenji (16 November 2004). "Selenophosphate synthetase genes from lung adenocarcinoma cells: Sps1 for recycling l -selenocysteine and Sps2 for selenite assimilation". Proceedings of the National Academy of Sciences. 101 (46): 16162–16167. Bibcode:2004PNAS..10116162T. doi:10.1073/pnas.0406313101. PMC 528966. PMID 15534230.
  6. ^ a b Rotter, Christiane; Schuster, Michael; Gebler, Sebastian; Klapötke, Thomas M.; Karaghiosoff, Konstantin (2010-04-19). "New Salts of the Waterstable P 2 Se 6 4− Anion". Inorganic Chemistry. 49 (8): 3937–3941. doi:10.1021/ic100200b. ISSN 0020-1669. PMID 20297773.
  7. ^ a b c d e Rothenberger, Alexander; Malliakas, Christos D.; Kanatzidis, Mercouri G. (July 2009). "Hydrated Alkali Metal and Ammonium Salts of the [P 2 Se 6 ] 4– Anion". Zeitschrift für anorganische und allgemeine Chemie. 635 (9–10): 1374–1379. doi:10.1002/zaac.200900184. ISSN 0044-2313.
  8. ^ a b c d Rotter, Christiane; Schuster, Michael; Kidik, Mustafa; Schön, Oliver; Klapötke, Thomas M.; Karaghiosoff, Konstantin (2008-03-01). "Structural and NMR Spectroscopic Investigations of Chair and Twist Conformers of the P 2 Se 8 2− Anion". Inorganic Chemistry. 47 (5): 1663–1673. doi:10.1021/ic7015534. ISSN 0020-1669. PMID 18237117.
  9. ^ Karaghiosoff, Konstantin; Schuster, Michael (2001-01-01). "Monomeric, Dimeric, and Trimeric Triselenometaphosphate". Phosphorus, Sulfur, and Silicon and the Related Elements. 168 (1): 117–122. doi:10.1080/10426500108546540. ISSN 1042-6507. S2CID 98688633.
  10. ^ Rotter, Christiane; Schuster, Michael; Karaghiosoff, Konstantin (2009-08-17). "An Unusual Binary Phosphorus−Tellurium Anion and Its Seleno- and Thio- Analogues: P 4 Ch 2 2− (Ch = S, Se, Te)". Inorganic Chemistry. 48 (16): 7531–7533. doi:10.1021/ic901149m. ISSN 0020-1669. PMID 19621885.
  11. ^ Zhang, Long; Yang, Kun; Mi, Jianli; Lu, Lei; Zhao, Linran; Wang, Limin; Li, Yueming; Zeng, Hong (December 2015). "Solid Electrolytes: Na 3 PSe 4 : A Novel Chalcogenide Solid Electrolyte with High Ionic Conductivity (Adv. Energy Mater. 24/2015)". Advanced Energy Materials. 5 (24). doi:10.1002/aenm.201570133. ISSN 1614-6832.
  12. ^ a b c Knaust, Jacqueline M.; Dorhout, Peter K. (March 2006). "Synthesis and structures of Na4P2Se6, Cs3PSe4, and Rb4P2Se9". Journal of Chemical Crystallography. 36 (3): 217–223. doi:10.1007/s10870-005-9050-8. ISSN 1074-1542. S2CID 96077297.
  13. ^ a b c Jörgens, Stefan; Mewis, Albrecht (January 2004). "Die Kristallstrukturen von Hexachalcogeno-Hypodiphosphaten des Magnesiums und Zinks". Zeitschrift für anorganische und allgemeine Chemie. 630 (1): 51–57. doi:10.1002/zaac.200300244. ISSN 0044-2313.
  14. ^ a b c d Haynes, Alyssa S.; Saouma, Felix O.; Otieno, Calford O.; Clark, Daniel J.; Shoemaker, Daniel P.; Jang, Joon I.; Kanatzidis, Mercouri G. (2015-03-10). "Phase-Change Behavior and Nonlinear Optical Second and Third Harmonic Generation of the One-Dimensional K (1– x ) Cs x PSe 6 and Metastable β-CsPSe 6". Chemistry of Materials. 27 (5): 1837–1846. doi:10.1021/acs.chemmater.5b00065. ISSN 0897-4756.
  15. ^ a b c Chung, In; Do, Junghwan; Canlas, Christian G.; Weliky, David P.; Kanatzidis, Mercouri G. (2004-05-01). "APSe 6 (A = K, Rb, and Cs): Polymeric Selenophosphates with Reversible Phase-Change Properties". Inorganic Chemistry. 43 (9): 2762–2764. doi:10.1021/ic035448q. ISSN 0020-1669. PMID 15106958.
  16. ^ a b Chung, In; Kim, Myung-Gil; Jang, Joon I.; He, Jiaqing; Ketterson, John B.; Kanatzidis, Mercouri G. (2011-11-11). "Strongly Nonlinear Optical Chalcogenide Thin Films of APSe 6 (A=K, Rb) from Spin-Coating". Angewandte Chemie International Edition. 50 (46): 10867–10870. doi:10.1002/anie.201103691. ISSN 1433-7851. PMID 21936037.
  17. ^ Jang, J. I.; Haynes, A. S.; Saouma, F. O.; Otieno, C. O.; Kanatzidis, M. G. (2013-09-01). "Broadband studies of the strong mid-infrared nonlinear optical responses of KPSe_6". Optical Materials Express. 3 (9): 1302. Bibcode:2013OMExp...3.1302J. doi:10.1364/OME.3.001302. ISSN 2159-3930.
  18. ^ Syrigos, Jonathan C.; Kanatzidis, Mercouri G. (2016-05-02). "Scandium Selenophosphates: Structure and Properties of K 4 Sc 2 (PSe 4 ) 2 (P 2 Se 6 )". Inorganic Chemistry. 55 (9): 4664–4668. doi:10.1021/acs.inorgchem.6b00535. ISSN 0020-1669. PMID 27078201.
  19. ^ a b c Chung, In; Malliakas, Christos D.; Jang, Joon I.; Canlas, Christian G.; Weliky, David P.; Kanatzidis, Mercouri G. (2007-12-01). "Helical Polymer 1 / ∞ [P 2 Se 6 2 - ]: Strong Second Harmonic Generation Response and Phase-Change Properties of Its K and Rb Salts". Journal of the American Chemical Society. 129 (48): 14996–15006. doi:10.1021/ja075096c. ISSN 0002-7863. PMID 17988126.
  20. ^ Dickerson, Christine A.; Fisher, Mary J.; Sykora, Richard E.; Albrecht-Schmitt, Thomas E.; Cody, Jason A. (2002-02-01). "Solvothermal Synthesis and Structure of a New Selenium-Rich Selenophosphate K 3 PSe 4 ·2Se 6". Inorganic Chemistry. 41 (4): 640–642. doi:10.1021/ic015602d. ISSN 0020-1669. PMID 11849062.
  21. ^ Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1998-05-01). "[P 8 Se 18 ] 6 - : A New Oligomeric Selenophosphate Anion with P 4+ and P 3+ Centers and Pyramidal [PSe 3 ] Fragments". Inorganic Chemistry. 37 (10): 2582–2584. doi:10.1021/ic980024v. ISSN 0020-1669.
  22. ^ a b c d Jörgens, Stefan; Mewis, Albrecht; Hoffmann, Rolf-Dieter; Pöttgen, Rainer; Mosel, Bernd D. (March 2003). "Neue Hexachalcogeno-Hypodiphosphate der Erdalkalimetalle und des Europiums". Zeitschrift für anorganische und allgemeine Chemie. 629 (3): 429–433. doi:10.1002/zaac.200390071. ISSN 0044-2313.
  23. ^ Syrigos, Jonathan C.; Kanatzidis, Mercouri G. (2016-05-02). "Scandium Selenophosphates: Structure and Properties of K 4 Sc 2 (PSe 4 ) 2 (P 2 Se 6 )". Inorganic Chemistry. 55 (9): 4664–4668. doi:10.1021/acs.inorgchem.6b00535. ISSN 0020-1669. PMID 27078201.
  24. ^ a b c d e f g h i j k Konstantinos, Chondroudis (1997). "Molten salt synthesis of multinary selenophosphates". ProQuest. Retrieved 2023-12-27.
  25. ^ Qian, Eric K.; Iyer, Abishek K.; Cheng, Matthew; Ryan, Kevin M.; Jirousek, Lillian; Chica, Daniel G.; Krantz, Patrick; Lee, Yea-Shine; Chandrasekhar, Venkat; Dravid, Vinayak P.; Kanatzidis, Mercouri G. (2023-05-09). "Synthesizing Mono- and Bimetallic 2D Selenophosphates Using a P 2 Se 5 Reactive Flux". Chemistry of Materials. 35 (9): 3671–3685. doi:10.1021/acs.chemmater.3c00342. ISSN 0897-4756. S2CID 258349455.
  26. ^ a b "Synthesis and Crystal Growth of 2D Layered Metal Chalophosphate Materials Using P2Q5 Reactive Fluxes - ProQuest". www.proquest.com. Retrieved 2024-11-06.
  27. ^ a b c d Chen, Xu; Wang, Junjie; Ying, Tianping; Huang, Dajian; Gou, Huiyang; Zhang, Qinghua; Li, Yanchun; Hosono, Hideo; Guo, Jian-gang; Chen, Xiaolong (2022-11-02). "Insulator-metal-superconductor transition in the medium-entropy van der Waals compound M P Se 3 ( M = Fe , Mn , Cd , and In ) under high pressure". Physical Review B. 106 (18): 184502. arXiv:2207.08589. doi:10.1103/PhysRevB.106.184502. ISSN 2469-9950. S2CID 250627324.
  28. ^ a b Du, Ke-zhao; Wang, Xing-zhi; Liu, Yang; Hu, Peng; Utama, M. Iqbal Bakti; Gan, Chee Kwan; Xiong, Qihua; Kloc, Christian (2016-02-23). "Weak Van der Waals Stacking, Wide-Range Band Gap, and Raman Study on Ultrathin Layers of Metal Phosphorus Trichalcogenides". ACS Nano. 10 (2): 1738–1743. doi:10.1021/acsnano.5b05927. ISSN 1936-0851. PMID 26607168.
  29. ^ a b c d e f g h McCarthy, Timothy J.; Kanatzidis, Mercouri G. (March 1995). "Synthesis in Molten Alkali Metal Polyselenophosphate Fluxes: A New Family of Transition Metal Selenophosphate Compounds, A2MP2Se6 (A = K, Rb, Cs; M = Mn, Fe) and A2M'2P2Se6 (A = K, Cs; M' = Cu, Ag)". Inorganic Chemistry. 34 (5): 1257–1267. doi:10.1021/ic00109a037. ISSN 0020-1669.
  30. ^ Li, Weiwei; Feng, Jiajia; Zhang, Xiaoliang; Li, Cong; Dong, Hongliang; Deng, Wen; Liu, Junxiu; Tian, Hua; Chen, Jian; Jiang, Sheng; Sheng, Hongwei; Chen, Bin; Zhang, Hengzhong (2021-12-08). "Metallization and Superconductivity in the van der Waals Compound CuP 2 Se through Pressure-Tuning of the Interlayer Coupling". Journal of the American Chemical Society. 143 (48): 20343–20355. doi:10.1021/jacs.1c09735. ISSN 0002-7863. PMID 34813695. S2CID 244529079.
  31. ^ a b c d e Kuhn, Alexander; Schoop, Leslie M.; Eger, Roland; Moudrakovski, Igor; Schwarzmüller, Stefan; Duppel, Viola; Kremer, Reinhard K.; Oeckler, Oliver; Lotsch, Bettina V. (2016-08-15). "Copper Selenidophosphates Cu 4 P 2 Se 6 , Cu 4 P 3 Se 4 , Cu 4 P 4 Se 3 , and CuP 2 Se, Featuring Zero-, One-, and Two-Dimensional Anions". Inorganic Chemistry. 55 (16): 8031–8040. doi:10.1021/acs.inorgchem.6b01161. ISSN 0020-1669. PMID 27447868.
  32. ^ Neisius, Nathan A.; MacHale, Luke T.; Snyder, Erin R.; Finke, Richard G.; Prieto, Amy L. (2023-12-27). "Copper Selenophosphate, Cu 3 PSe 4 , Nanoparticle Synthesis: Octadecane Is the Key to a Simplified, Atom-Economical Reaction". Nano Letters. 23 (24): 11430–11437. Bibcode:2023NanoL..2311430N. doi:10.1021/acs.nanolett.3c02620. ISSN 1530-6984. PMID 38085913. S2CID 266217367.
  33. ^ Pfeiff, Regine; Kniep, Rüdiger (1993-09-01). "Darstellung von quaternären Selenodiphosphaten(IV) aus Halogenidschmelzen: Die Kristallstruktur des CuAl[P 2 Se 6 ] / Preparation of Quaternary Selenodiphosphates(IV) from Halide Melts: The Crystal Structure of CuAl[P 2 Se 6 ]". Zeitschrift für Naturforschung B. 48 (9): 1270–1274. doi:10.1515/znb-1993-0916. ISSN 1865-7117.
  34. ^ Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1998-05-01). "Flux Synthesis of K 2 Cu 2 P 4 Se 10 : A Layered Selenophosphate with a New Cyclohexane-like [P 4 Se 10 ] 4 - Group". Inorganic Chemistry. 37 (9): 2098–2099. doi:10.1021/ic971539+. ISSN 0020-1669. PMID 11670358.
  35. ^ a b c d e f g h i j Chen, John H.; Dorhout, Peter K. (November 1995). "Synthesis and Structural Characterization of a New Rare-Earth Selenodiphosphate: KLaP2Se6". Inorganic Chemistry. 34 (23): 5705–5706. doi:10.1021/ic00127a003. ISSN 0020-1669.
  36. ^ Dorhout, Peter K.; Malo, Todd M. (March 1996). "A three-dimensional network structure built from selenodiphosphate(IV) and copper selenide tetrahedral building blocks: K 3 Cu 3 P 3 Se 9". Zeitschrift für anorganische und allgemeine Chemie. 622 (3): 385–391. doi:10.1002/zaac.19966220302. ISSN 0044-2313.
  37. ^ a b Liu, C. W.; Chen, Hsiu-Chih; Wang, Ju-Chung; Keng, Tai-Chiun (2001-06-18). "[Cu12(P2Se6){Se2P(OR)2}8]: Discrete Copper Clusters Containing an Ethane-Like Hexaselenodiphosphate(IV)". Angewandte Chemie (in German). 113 (12): 2404–2406. doi:10.1002/1521-3757(20010618)113:12<2404::AID-ANGE2404>3.0.CO;2-7. ISSN 0044-8249.
  38. ^ a b c d e f Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (July 1998). "Group 10 and Group 12 One-Dimensional Selenodiphosphates:A2MP2Se6(A=K, Rb, Cs;M=Pd, Zn, Cd, Hg)". Journal of Solid State Chemistry. 138 (2): 321–328. doi:10.1006/jssc.1998.7791.
  39. ^ a b c Haynes, Alyssa S.; Lee, Katherine; Kanatzidis, Mercouri G. (September 2016). "One-Dimensional Zinc Selenophosphates: A 2 ZnP 2 Se 6 ( A = K, Rb, Cs)". Zeitschrift für anorganische und allgemeine Chemie. 642 (19): 1120–1125. doi:10.1002/zaac.201600231. ISSN 0044-2313.
  40. ^ a b c Morris, Collin D.; Chung, In; Park, Sungoh; Harrison, Connor M.; Clark, Daniel J.; Jang, Joon I.; Kanatzidis, Mercouri G. (2012-12-26). "Molecular Germanium Selenophosphate Salts: Phase-Change Properties and Strong Second Harmonic Generation". Journal of the American Chemical Society. 134 (51): 20733–20744. doi:10.1021/ja309386e. ISSN 0002-7863. PMID 23157167.
  41. ^ a b Morris, Collin D.; Malliakas, Christos D.; Kanatzidis, Mercouri G. (2011-10-17). "Germanium Selenophosphates: The Incommensurately Modulated 1 / ∞ [Ge 4-x P x Se 12 4– ] and the Molecular [Ge 2 P 2 Se 14 ] 6–". Inorganic Chemistry. 50 (20): 10241–10248. doi:10.1021/ic201249w. ISSN 0020-1669. PMID 21928764.
  42. ^ a b c d Morris, Collin D.; Kanatzidis, Mercouri G. (2010-10-04). "Arsenic-Containing Chalcophosphate Molecular Anions". Inorganic Chemistry. 49 (19): 9049–9054. doi:10.1021/ic101461w. ISSN 0020-1669. PMID 20825231.
  43. ^ Chung, In; Karst, Angela L.; Weliky, David P.; Kanatzidis, Mercouri G. (2006-04-01). "[P 6 Se 12 ] 4 - : A Phosphorus-Rich Selenophosphate with Low-Valent P Centers". Inorganic Chemistry. 45 (7): 2785–2787. doi:10.1021/ic0601135. ISSN 0020-1669. PMID 16562935.
  44. ^ a b Chondroudis, Konstantinos; Kanatzidis, Mercouri G (February 1998). "[Ce(PSe4)4]9−: a highly anionic Ce3+ selenophosphate coordination complex". Inorganic Chemistry Communications. 1 (2): 55–57. doi:10.1016/S1387-7003(98)00011-2.
  45. ^ Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (October 1995). "Complex Multinary Compounds from Molten Alkali Metal Polyselenophosphate Fluxes. Layers and Chains in A4Ti2(P2Se9)2(P2Se7) and ATiPSe5 (A = K, Rb). Isolation of 4-, a Flux Constituent Anion". Inorganic Chemistry. 34 (22): 5401–5402. doi:10.1021/ic00126a004. ISSN 0020-1669.
  46. ^ a b c d e f g h i j k Zhao, Chen-Yi; Chen, Zi-Xia; Yao, Wen-Dong; Zhou, Wenfeng; Liu, Wenlong; Guo, Sheng-Ping (11 December 2023). "NaREP 2 Se 6 (RE = Y, Sm, Gd–Dy): Quaternary Rare-Earth Selenophosphates with Unique 3D { − } ∞ Framework Built by RESe 8 and P 2 Se 6 Motifs and Multiple Properties". Inorganic Chemistry. 62 (49): 19843–19847. doi:10.1021/acs.inorgchem.3c03695. PMID 38032849. S2CID 265515288.
  47. ^ Zhao, Chen-Yi; Chen, Zi-Xia; Yao, Wen-Dong; Zhou, Wenfeng; Liu, Wenlong; Guo, Sheng-Ping (2023-12-11). "NaREP 2 Se 6 (RE = Y, Sm, Gd–Dy): Quaternary Rare-Earth Selenophosphates with Unique 3D {[REP 2 Se 6 ] − } ∞ Framework Built by RESe 8 and P 2 Se 6 Motifs and Multiple Properties". Inorganic Chemistry. 62 (49): 19843–19847. doi:10.1021/acs.inorgchem.3c03695. ISSN 0020-1669. PMID 38032849. S2CID 265515288.
  48. ^ Chen, John H.; Dorhout, Peter K.; Ostenson, J. E. (1996-01-01). "A Comparative Study of Two New Structure Types. Synthesis and Structural and Electronic Characterization of K(RE)P 2 Se 6 (RE = Y, La, Ce, Pr, Gd)". Inorganic Chemistry. 35 (19): 5627–5633. doi:10.1021/ic9516121. ISSN 0020-1669. PMID 11666755.
  49. ^ Seitz, A. E.; Heinl, V.; Timoshkin, A. Y.; Scheer, M. (2017). "Transformation of nortricyclane type cage compounds P 4 S 3 , P 4 Se 3 and As 4 S 3 by [Cp′′ 2 Zr(CO) 2 ]". Chemical Communications. 53 (6): 1172–1175. doi:10.1039/C6CC09427A. ISSN 1359-7345. PMID 28054088.
  50. ^ a b c Banerjee, Santanu; Malliakas, Christos D.; Jang, Joon I.; Ketterson, John B.; Kanatzidis, Mercouri G. (2008-09-17). "1 / ∞ [ZrPSe 6 − ]: A Soluble Photoluminescent Inorganic Polymer and Strong Second Harmonic Generation Response of Its Alkali Salts". Journal of the American Chemical Society. 130 (37): 12270–12272. doi:10.1021/ja804166m. ISSN 0002-7863. PMID 18715000.
  51. ^ a b c Syrigos, Jonathan C.; Clark, Daniel J.; Saouma, Felix O.; Clarke, Samantha M.; Fang, Lei; Jang, Joon I.; Kanatzidis, Mercouri G. (2015-01-13). "Semiconducting Properties and Phase-Matching Nonlinear Optical Response of the One-Dimensional Selenophosphates ANb 2 PSe 10 (A = K, Rb, and Cs)". Chemistry of Materials. 27 (1): 255–265. doi:10.1021/cm5038217. ISSN 0897-4756.
  52. ^ Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1997-07-04). "[P 3 Se]: A Novel Polyanion in K 3 RuP 5 Se 10 ; Formation of RuP Bonds in a Molten Polyselenophosphate Flux". Angewandte Chemie International Edition in English. 36 (12): 1324–1326. doi:10.1002/anie.199713241. ISSN 0570-0833.
  53. ^ Duan, Ruihuan; Zhu, Chao; Zeng, Qingsheng; Wang, Xiaowei; Gao, Yang; Deng, Ya; He, Yanchao; Yang, Jiefu; Zhou, Jiadong; Xu, Manzhang; Liu, Zheng (August 2021). "PdPSe: Component-Fusion-Based Topology Designer of Two-Dimensional Semiconductor". Advanced Functional Materials. 31 (35). doi:10.1002/adfm.202102943. ISSN 1616-301X. S2CID 237883693.
  54. ^ Xia, Houping; Ma, Qian (April 2019). "Experimental study on nonlinear−optical property of Ag4P2Se6". Journal of Alloys and Compounds. 780: 727–733. doi:10.1016/j.jallcom.2018.11.403. S2CID 139703145.
  55. ^ Susner, Michael A.; Conner, Benjamin S.; Rowe, Emmanuel; Siebenaller, Ryan; Giordano, Andrea; McLeod, Michael V.; Ebbing, Charles R.; Bullard, Thomas J.; Selhorst, Ryan; Haugan, Timothy J.; Jiang, Jie; Pachter, Ruth; Rao, Rahul (2024-03-02). "Structural, Magnetic, and Optical Properties of the van der Waals Antiferromagnet AgCrP 2 Se 6". The Journal of Physical Chemistry C. doi:10.1021/acs.jpcc.3c07433. ISSN 1932-7447.
  56. ^ a b c Pfitzner, Arno; Seidlmayer, Stefan (April 2009). "Synthesis and Structure Determination of AgScP 2 Se 6 , AgErP 2 Se 6 and AgTmP 2 Se 6". Zeitschrift für anorganische und allgemeine Chemie. 635 (4–5): 704–707. doi:10.1002/zaac.200900004. ISSN 0044-2313. S2CID 94646944.
  57. ^ Chica, Daniel G.; He, Yihui; McCall, Kyle M.; Chung, Duck Young; Pak, Rahmi O.; Trimarchi, Giancarlo; Liu, Zhifu; De Lurgio, Patrick M.; Wessels, Bruce W.; Kanatzidis, Mercouri G. (2020-01-16). "Direct thermal neutron detection by the 2D semiconductor 6LiInP2Se6". Nature. 577 (7790): 346–349. doi:10.1038/s41586-019-1886-8. ISSN 0028-0836. PMID 31942050. S2CID 210221831.
  58. ^ a b Chondroudis, Konstantinos; Chakrabarty, Debojit; Axtell, Enos A.; Kanatzidis, Mercouri G. (June 1998). "Synthesis of the One-dimensional Compound (Ph4P)[In(P2Se6)] in a Ph4P+-Containing Selenophosphate Flux, and Structure of [In(P2Se6)2]5- - a Discrete Molecular Fragment of the [In(P2Se6)]nn- Chain". Zeitschrift für anorganische und allgemeine Chemie (in German). 624 (6): 975–979. doi:10.1002/(SICI)1521-3749(199806)624:6<975::AID-ZAAC975>3.0.CO;2-1. ISSN 0044-2313.
  59. ^ Coste, Servane; Kopnin, Evgeni; Evain, Michel; Jobic, Stéphane; Brec, Raymond; Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (April 2002). "Polychalcogenophosphate flux synthesis of 1D-KInP2Se6 and 1D and 3D-NaCrP2S6". Solid State Sciences. 4 (5): 709–716. doi:10.1016/S1293-2558(02)01317-1.
  60. ^ a b c Rothenberger, Alexander; Wang, Hsien-Hau; Chung, DuckYoung; Kanatzidis, Mercouri G. (2010-02-01). "Structural Diversity by Mixing Chalcogen Atoms in the Chalcophosphate System K/In/P/Q (Q = S, Se)". Inorganic Chemistry. 49 (3): 1144–1151. doi:10.1021/ic902105j. ISSN 0020-1669. PMID 20030374.
  61. ^ a b Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (February 1998). "K4In2(PSe5)2(P2Se6) and Rb3Sn(PSe5)(P2Se6): One-Dimensional Compounds with Mixed Selenophosphate Anions". Journal of Solid State Chemistry. 136 (1): 79–86. doi:10.1006/jssc.1997.7659.
  62. ^ Zhang, Cheng-gong; Ji, Wei-xiao; Li, Ping; Zhang, Chang-wen; Wang, Pei-Ji (October 2021). "Tuning the electronic and optical properties of two-dimensional AgBiP2Se6 and AgInP2Se6 Janus monolayers". Chemical Physics Letters. 780: 138933. doi:10.1016/j.cplett.2021.138933.
  63. ^ Chica, Daniel; Sangwan, Vinod; Chu, Ting-Ching; Cheng, Matthew; Quintero, Michael; Hao, Shiqiang; Choi, Hyeonseon; Liu, Yukun; Qian, Eric (2022-10-17). SnP2Se6: A Chiral 2D Semiconductor for High-Performance Electronics and Optoelectronics (Report). In Review. doi:10.21203/rs.3.rs-2143024/v1.
  64. ^ Eijt, S; Maior, M.M (May 1999). "Raman and infrared hard mode spectroscopy of the internal vibrations in Sn2P2Se6". Journal of Physics and Chemistry of Solids. 60 (5): 631–643. Bibcode:1999JPCS...60..631E. doi:10.1016/S0022-3697(98)00319-9.
  65. ^ Duchardt, Marc; Neuberger, Sven; Ruschewitz, Uwe; Krauskopf, Thorben; Zeier, Wolfgang G.; Schmedt auf der Günne, Jörn; Adams, Stefan; Roling, Bernhard; Dehnen, Stefanie (2018-06-26). "Superion Conductor Na 11.1 Sn 2.1 P 0.9 Se 12 : Lowering the Activation Barrier of Na + Conduction in Quaternary 1–4–5–6 Electrolytes". Chemistry of Materials. 30 (12): 4134–4139. doi:10.1021/acs.chemmater.8b01656. ISSN 0897-4756.
  66. ^ a b Chung, In; Kanatzidis, Mercouri G. (2011-01-17). "Stabilization of Sn 2+ in K 10 Sn 3 (P 2 Se 6 ) 4 and Cs 2 SnP 2 Se 6 Derived from a Basic Flux". Inorganic Chemistry. 50 (2): 412–414. doi:10.1021/ic101140r. ISSN 0020-1669. PMID 21142146.
  67. ^ Chung, In; Biswas, Kanishka; Song, Jung-Hwan; Androulakis, John; Chondroudis, Konstantinos; Paraskevopoulos, Konstantinos M.; Freeman, Arthur J.; Kanatzidis, Mercouri G. (2011-09-12). "Rb 4 Sn 5 P 4 Se 20 : A Semimetallic Selenophosphate". Angewandte Chemie International Edition. 50 (38): 8834–8838. doi:10.1002/anie.201104050. ISSN 1433-7851. PMID 21812086.
  68. ^ Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1998-06-01). "Rb 4 Sn 2 Ag 4 (P 2 Se 6 ) 3 : First Example of a Quinary Selenophosphate and an Unusual Sn−Ag s 2 −d 10 Interaction". Inorganic Chemistry. 37 (12): 2848–2849. doi:10.1021/ic971468e. ISSN 0020-1669.
  69. ^ a b Chondroudis, Konstantinos; Kanatizidis, Mercouri G. (1996). "Isolation of [Sn(PSe 5 ) 3 ] 5– and [Sn 2 Se 4 (PSe 5 ) 2 ] 6– ; the first discrete complexes from molten alkali-metal polyselenophosphate fluxes". Chem. Commun. (11): 1371–1372. doi:10.1039/CC9960001371. ISSN 1359-7345.
  70. ^ a b Ruck, Michael (August 1995). "Darstellung und Kristallstruktur der Hexaselenodiphosphate(IV) von Antimon und Bismut". Zeitschrift für anorganische und allgemeine Chemie. 621 (8): 1344–1350. doi:10.1002/zaac.19956210812. ISSN 0044-2313.
  71. ^ a b Breshears, Jean D.; Kanatzidis, Mercouri G. (2000-08-01). "β-KMP 2 Se 6 (M = Sb, Bi): Kinetically Accessible Phases Obtained from Rapid Crystallization of Amorphous Precursors". Journal of the American Chemical Society. 122 (32): 7839–7840. doi:10.1021/ja001270k. ISSN 0002-7863.
  72. ^ Vu, Tuan V.; Lavrentyev, A.A.; Gabrelian, B.V.; Vo, Dat D.; Sabov, V.I.; Sabov, M.Yu.; Barchiy, I.E.; Piasecki, M.; Khyzhun, O.Y. (August 2020). "Highly anisotropic layered selenophosphate AgSbP2Se6: The electronic structure and optical properties by experimental measurements and first-principles calculations". Chemical Physics. 536: 110813. doi:10.1016/j.chemphys.2020.110813. S2CID 219077317.
  73. ^ a b c Haynes, Alyssa S.; Banerjee, Abhishek; Saouma, Felix O.; Otieno, Calford O.; Jang, Joon I.; Kanatzidis, Mercouri G. (2016-04-12). "Phase Transition, Conformational Exchange, and Nonlinear Optical Third Harmonic Generation of A CsP 2 Se 8 ( A = K, Rb, Cs)". Chemistry of Materials. 28 (7): 2374–2383. doi:10.1021/acs.chemmater.6b00551. ISSN 0897-4756.
  74. ^ Gave, Matthew A.; Canlas, Christian G.; Chung, In; Iyer, Ratnasabapathy G.; Kanatzidis, Mercouri G.; Weliky, David P. (October 2007). "Cs4P2Se10: A new compound discovered with the application of solid-state and high temperature NMR". Journal of Solid State Chemistry. 180 (10): 2877–2884. doi:10.1016/j.jssc.2007.08.002.
  75. ^ a b Chung, In; Jang, Joon I.; Gave, Matthew A.; Weliky, David P.; Kanatzidis, Mercouri G. (2007). "Low valent phosphorus in the molecular anions 5– and β-4–: phase change behavior and near infrared second harmonic generation". Chemical Communications (47): 4998–5000. doi:10.1039/b714301j. ISSN 1359-7345. PMID 18049732.
  76. ^ a b c 李, 梦月; 谢, 秀媛; 吴, 新涛; 李, 晓芳; 林, 华 (2021). "Quaternary Selenophosphate Cs_2ZnP_2Se_6 Featuring Unique One-dimensional Chains and Exhibiting Remarkable Photo-electrochemical Response". Chinese Journal of Structural Chemistry. 40 (2): 246–255. doi:10.14102/j.cnki.0254-5861.2011-2822. ISSN 0254-5861.
  77. ^ Chung, In; Holmes, Daniel; Weliky, David P.; Kanatzidis, Mercouri G. (2010-04-05). "[P 3 Se 7 ] 3− : A Phosphorus-Rich Square-Ring Selenophosphate". Inorganic Chemistry. 49 (7): 3092–3094. doi:10.1021/ic902561h. ISSN 0020-1669. PMID 20180545.
  78. ^ a b c Chondroudis, Konstantinos; Kanatzidis, Mercouri G.; Sayettat, Julien; Jobic, Stéphane; Brec, Raymond (1997-12-01). "Palladium Chemistry in Molten Alkali Metal Polychalcophosphate Fluxes. Synthesis and Characterization of K 4 Pd(PS 4 ) 2 , Cs 4 Pd(PSe 4 ) 2 , Cs 10 Pd(PSe 4 ) 4 , KPdPS 4 , K 2 PdP 2 S 6 , and Cs 2 PdP 2 Se 6". Inorganic Chemistry. 36 (25): 5859–5868. doi:10.1021/ic970593n. ISSN 0020-1669. PMID 11670209.
  79. ^ a b c Haynes, Alyssa S.; Stoumpos, Constantinos C.; Chen, Haijie; Chica, Daniel; Kanatzidis, Mercouri G. (2017-08-09). "Panoramic Synthesis as an Effective Materials Discovery Tool: The System Cs/Sn/P/Se as a Test Case". Journal of the American Chemical Society. 139 (31): 10814–10821. doi:10.1021/jacs.7b05423. ISSN 0002-7863. PMID 28665593.
  80. ^ a b Galdámez, A; Manrı́quez, V; Kasaneva, J; Avila, R.E (May 2003). "Synthesis, characterization and electrical properties of quaternary selenodiphosphates: AMP2SE6 with A = Cu, Ag and M = Bi, Sb". Materials Research Bulletin. 38 (6): 1063–1072. doi:10.1016/S0025-5408(03)00068-0.
  81. ^ a b c Jörgens, Stefan; Mewis, Albrecht (2005-04-01). "Neue Chalcogenophosphate: KBaPS 4 , KBaPSe 4 und Ba 3 PO 4 PSe 4 / New Chalcogenophosphates: KBaPS 4 , KBaPSe 4 , and Ba 3 PO 4 PSe 4". Zeitschrift für Naturforschung B. 60 (4): 431–436. doi:10.1515/znb-2005-0414. ISSN 1865-7117.
  82. ^ Jörgens, Stefan; Mewis, Albrecht (April 2007). "Synthese und Kristallstrukturen von α- und β -Ba 3 (PS 4 ) 2 sowie von Ba 3 (PSe 4 ) 2". Zeitschrift für anorganische und allgemeine Chemie. 633 (4): 570–574. doi:10.1002/zaac.200600360. ISSN 0044-2313.
  83. ^ a b c d e Evenson; Dorhout, Peter K. (2001-06-01). "Selenophosphate Phase Diagrams Developed in Conjunction with the Synthesis of the New Compounds K 2 La(P 2 Se 6 ) 1/2 (PSe 4 ), K 3 La(PSe 4 ) 2 , K 4 La 0.67 (PSe 4 ) 2 , K 9- x La 1+ x /3 (PSe 4 ) 4 ( x = 0.5), and KEuPSe 4". Inorganic Chemistry. 40 (12): 2875–2883. doi:10.1021/ic000595z. ISSN 0020-1669. PMID 11375707.
  84. ^ Dorhout, Peter K.; Evenson, Carl R. (2001), Hochheimer, Hans D.; Kuchta, Bogdan; Dorhout, Peter K.; Yarger, Jeffery L. (eds.), "Synthesis of Low Dimensional F-Element Chalcogenide Compounds", Frontiers of High Pressure Research II: Application of High Pressure to Low-Dimensional Novel Electronic Materials, Dordrecht: Springer Netherlands, pp. 13–27, doi:10.1007/978-94-010-0520-3_2, ISBN 978-1-4020-0160-4, retrieved 2023-12-27
  85. ^ a b c d Aitken, Jennifer A.; Evain, Michel; Iordanidis, Lykourgos; Kanatzidis, Mercouri G. (2002-01-01). "NaCeP 2 Se 6 , Cu 0.4 Ce 1.2 P 2 Se 6 , Ce 4 (P 2 Se 6 ) 3 , and the Incommensurately Modulated AgCeP 2 Se 6 : New Selenophosphates Featuring the Ethane-Like [P 2 Se 6 ] 4 - Anion". Inorganic Chemistry. 41 (2): 180–191. doi:10.1021/ic010618p. ISSN 0020-1669. PMID 11800606.
  86. ^ a b c d Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1998-07-01). "New Lanthanide Selenophosphates. Influence of Flux Composition on the Distribution of [PSe 4 ] 3 - /[P 2 Se 6 ] 4 - Units and the Stabilization of the Low-Dimensional Compounds A 3 REP 2 Se 8 , and A 2 (RE)P 2 Se 7 (A = Rb, Cs; RE = Ce, Gd)". Inorganic Chemistry. 37 (15): 3792–3797. doi:10.1021/ic980025n. ISSN 0020-1669. PMID 11670481.
  87. ^ a b c Schulz, Beate M.; Lange, Pia L.; Schleid, Thomas (2020-11-26). "Three of a kind? The non-isotypic triple CsCe[P 2 Se 6 ], CsSm[P 2 Se 6 ] and CsEr[P 2 Se 6 ]". Zeitschrift für Naturforschung B. 75 (11): 959–967. doi:10.1515/znb-2020-0148. ISSN 1865-7117. S2CID 226968695.
  88. ^ 26th Annual Conference of the German Crystallographic Society, March 5–8, 2018, Essen, Germany. Walter de Gruyter GmbH & Co KG. 2018-03-05. p. 97. ISBN 978-3-11-059599-4.
  89. ^ a b Aitken, Jennifer A.; Chondroudis, Konstantinos; Young, Victor G.; Kanatzidis, Mercouri G. (2000-04-01). "LiEuPSe 4 and KEuPSe 4 : Novel Selenophosphates with the Tetrahedral [PSe 4 ] 3 - Building Block". Inorganic Chemistry. 39 (7): 1525–1533. doi:10.1021/ic991090f. ISSN 0020-1669. PMID 12526459.
  90. ^ a b Martin, Benjamin R.; Polyakova, Larisa A.; Dorhout, Peter K. (February 2006). "Synthesis and characterization of a family of two related quaternary selenides: Na8Eu2(Si2Se6)2 and Na9Sm(Ge2Se6)2". Journal of Alloys and Compounds. 408–412: 490–495. doi:10.1016/j.jallcom.2004.12.091.
  91. ^ a b c d e Chondroudis, Konstantinos; McCarthy, Timothy J.; Kanatzidis, Mercouri G. (1996-01-01). "Chemistry in Molten Alkali Metal Polyselenophosphate Fluxes. Influence of Flux Composition on Dimensionality. Layers and Chains in APbPSe 4 , A 4 Pb(PSe 4 ) 2 (A = Rb, Cs), and K 4 Eu(PSe 4 ) 2". Inorganic Chemistry. 35 (4): 840–844. doi:10.1021/ic950479+. ISSN 0020-1669. PMID 11666254.
  92. ^ a b c Chen, Zi-Xia; Zhao, Chen-Yi; Li, Xiao-Hui; Yao, Wen-Dong; Liu, Wenlong; Guo, Sheng-Ping (February 2023). "KREP 2 Se 6 (RE = Sm, Gd, Tb): The First Rare-Earth Selenophosphates with Remarkable Nonlinear Optical Activities Realized by Synergistic Effect of RE- and P-Based Motifs". Small. 19 (8): e2206910. doi:10.1002/smll.202206910. ISSN 1613-6810. PMID 36504482. S2CID 254617594.
  93. ^ Orgzall, I.; Lorenz, B.; Dorhout, P.K.; Van Calcar, P.M.; Brister, K.; Sander, T.; Hochheimer, H.D. (January 2000). "High pressure optical and X-ray diffraction studies of two polymorphs of K(RE)P2Se6 (RE=Pr and Tb)". Journal of Physics and Chemistry of Solids. 61 (1): 123–134. Bibcode:2000JPCS...61..123O. doi:10.1016/S0022-3697(99)00012-8.
  94. ^ a b c d e Chondroudis, Konstantinos; Hanko, Jason A.; Kanatzidis, Mercouri G. (1997-06-01). "Chemistry of Gold in Molten Alkali Metal Polychalcophosphate Fluxes. Synthesis and Characterization of the Low-Dimensional Compounds A 3 AuP 2 Se 8 (A = K, Rb, Cs), A 2 Au 2 P 2 Se 6 (A = K, Rb), A 2 AuPS 4 (A = K, Rb, Cs), and AAuP 2 S 7 (A = K, Rb)". Inorganic Chemistry. 36 (12): 2623–2632. doi:10.1021/ic961376+. ISSN 0020-1669.
  95. ^ Chondroudis, Konstantinos; McCarthy, Timothy J.; Kanatzidis, Mercouri G. (1996-01-01). "A 2 AuP 2 Se 6 (A = K, Rb): Mixed-Valent Compounds with All Possible Coordination Geometries for Gold". Inorganic Chemistry. 35 (12): 3451–3452. doi:10.1021/ic9516020. ISSN 0020-1669.
  96. ^ Brockner, Wolfgang; Pätzmann, Ulrich (1987-05-01). "Schwingungsspektrum des Quecksilber-Hexaselenidohypodiphosphates Hg 2 P 2 Se 6". Zeitschrift für Naturforschung A. 42 (5): 517–518. doi:10.1515/zna-1987-0518. ISSN 1865-7109.
  97. ^ Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1997). "[M4(Se2)2(PSe4)4 ]8−: a novel, tetranuclear, cluster anion with a stellane-like core". Chemical Communications (4): 401–402. doi:10.1039/a607549e.
  98. ^ a b Nawaz, Zeeshan (2017-12-01). "Methyl-Tert-Butyl-Ether Synthesis Reactor Modelling and Optimization Using an Aspen Custom Modeler" (PDF). Hungarian Journal of Industry and Chemistry. 45 (2): 1–7. doi:10.1515/hjic-2017-0012. ISSN 2450-5102.
  99. ^ Barchii, I. E.; Tovt, V. A.; Piasecki, M.; Fedorchuk, A. A.; Solomon, A. M.; Pogodin, A. I. (April 2018). "Physicochemical Interaction in the TlInSe2–TlInP2Se6 System". Russian Journal of Inorganic Chemistry. 63 (4): 537–542. doi:10.1134/S0036023618040034. ISSN 0036-0236. S2CID 102636407.
  100. ^ Vu, Tuan V.; Lavrentyev, A.A.; Gabrelian, B.V.; Sabov, V.I.; Sabov, M.Y.; Pogodin, A.I.; Barchiy, I.E.; Fedorchuk, A.O.; Balinska, A.; Bak, Z.; Khyzhun, O.Y.; Piasecki, M. (December 2020). "TlSbP2Se6 - a new layered single crystal: growth, structure and electronic properties". Journal of Alloys and Compounds. 848: 156485. doi:10.1016/j.jallcom.2020.156485. S2CID 225134562.
  101. ^ Wang, Peng L.; Liu, Zhifu; Chen, Pice; Peters, John A.; Tan, Gangjian; Im, Jino; Lin, Wenwen; Freeman, Arthur J.; Wessels, Bruce W.; Kanatzidis, Mercouri G. (August 2015). "Hard Radiation Detection from the Selenophosphate Pb 2 P 2 Se 6". Advanced Functional Materials. 25 (30): 4874–4881. doi:10.1002/adfm.201501826. ISSN 1616-301X. S2CID 93827410.
  102. ^ Becker, Robert; Brockner, Wolfgang; Schäfer, Herbert (1984-04-01). "Kristallstruktur und Schwingungsspektren des Di-Blei-Hexaselenohypodiphosphates Pb 2 P 2 Se 6 / Crystal Structure and Vibrational Spectra of Pb 2 P 2 Se 6". Zeitschrift für Naturforschung A. 39 (4): 357–361. doi:10.1515/zna-1984-0407. ISSN 1865-7109.
  103. ^ Aitken, Jennifer A.; Marking, Gregory A.; Evain, Michel; Iordanidis, Lykourgos; Kanatzidis, Mercouri G. (August 2000). "Flux Synthesis and Isostructural Relationship of Cubic Na1.5Pb0.75PSe4, Na0.5Pb1.75GeS4, and Li0.5Pb1.75GeS4". Journal of Solid State Chemistry. 153 (1): 158–169. doi:10.1006/jssc.2000.8767.
  104. ^ Qian, Eric K.; Iyer, Abishek K.; Cheng, Matthew; Ryan, Kevin M.; Jirousek, Lillian; Chica, Daniel G.; Krantz, Patrick; Lee, Yea-Shine; Chandrasekhar, Venkat; Dravid, Vinayak P.; Kanatzidis, Mercouri G. (2023-05-09). "Synthesizing Mono- and Bimetallic 2D Selenophosphates Using a P 2 Se 5 Reactive Flux". Chemistry of Materials. 35 (9): 3671–3685. doi:10.1021/acs.chemmater.3c00342. ISSN 0897-4756. S2CID 258349455.
  105. ^ a b Gave, Matthew A.; Bilc, Daniel; Mahanti, S. D.; Breshears, Jean D.; Kanatzidis, Mercouri G. (2005-07-01). "On the Lamellar Compounds CuBiP 2 Se 6 , AgBiP 2 Se 6 and AgBiP 2 S 6 . Antiferroelectric Phase Transitions Due to Cooperative Cu + and Bi 3+ Ion Motion". Inorganic Chemistry. 44 (15): 5293–5303. doi:10.1021/ic050357+. ISSN 0020-1669. PMID 16022528.
  106. ^ He, Wei; Kong, Lingling; Yu, Peng; Yang, Guowei (April 2023). "Record-High Work-Function p-Type CuBiP 2 Se 6 Atomic Layers for High-Photoresponse van der Waals Vertical Heterostructure Phototransistor". Advanced Materials. 35 (14): e2209995. Bibcode:2023AdM....3509995H. doi:10.1002/adma.202209995. ISSN 0935-9648. PMID 36640444. S2CID 255825402.
  107. ^ Chung, In; Song, Jung-Hwan; Jang, Joon I.; Freeman, Arthur J.; Ketterson, John B.; Kanatzidis, Mercouri G. (2009-02-25). "Flexible Polar Nanowires of Cs 5 BiP 4 Se 12 from Weak Interactions between Coordination Complexes: Strong Nonlinear Optical Second Harmonic Generation". Journal of the American Chemical Society. 131 (7): 2647–2656. doi:10.1021/ja808242g. ISSN 0002-7863. PMID 19183006.
  108. ^ a b Gave, Matthew A.; Malliakas, Christos D.; Weliky, David P.; Kanatzidis, Mercouri G. (2007-04-30). "Wide Compositional and Structural Diversity in the System Tl/Bi/P/Q (Q = S, Se) and Observation of Vicinal P−Tl J Coupling in the Solid State". Inorganic Chemistry. 46 (9): 3632–3644. doi:10.1021/ic062465h. ISSN 0020-1669. PMID 17397145.
  109. ^ a b c Briggs Piccoli, Paula M.; Abney, Kent D.; Schoonover, Jon R.; Dorhout, Peter K. (2000-07-01). "Synthesis and Structural Characterization of Quaternary Thorium Selenophosphates: A 2 ThP 3 Se 9 (A = K, Rb) and Cs 4 Th 2 P 5 Se 17". Inorganic Chemistry. 39 (14): 2970–2976. doi:10.1021/ic990767w. ISSN 0020-1669. PMID 11196891.
  110. ^ Briggs-Piccoli, Paula M.; Abney, Kent D.; Dorhout, Peter K. (November 2002). "The Synthesis and Structural Characterization of a New Beta Phase of K 2 ThP 3 Se 9". Journal of Nuclear Science and Technology. 39 (sup3): 611–615. Bibcode:2002JNST...39S.611B. doi:10.1080/00223131.2002.10875542. ISSN 0022-3131.
  111. ^ Chan, Benny C.; Hess, Ryan F.; Feng, Patrick L.; Abney, Kent D.; Dorhout, Peter K. (2005-03-21). "Synthesis and Characterization of Two Quaternary Thorium Chalcophosphates: Cs 4 Th 2 P 6 S 18 and Rb 7 Th 2 P 6 Se 21". Inorganic Chemistry. 44 (6): 2106–2113. doi:10.1021/ic049101e. ISSN 0020-1669. PMID 15762739.
  112. ^ Briggs Piccoli, Paula M.; Abney, Kent D.; Schoonover, Jon D.; Dorhout, Peter K. (2001-09-01). "Synthesis, Structure, and Properties of Cs 4 Th 4 P 4 Se 26 : A Quaternary Thorium Selenophosphate Containing the (P 2 Se 9 ) 6 - Anion". Inorganic Chemistry. 40 (19): 4871–4875. doi:10.1021/ic001103l. ISSN 0020-1669. PMID 11531433.
  113. ^ K., Chondroudis; M.G., Kanatzidis (1996). "Synthesis and characterization of K2UP3Se9. The first actinide seleno-phosphate". Comptes Rendus de l'Académie des Sciences, Série 2. 322 (12). ISSN 1251-8069.
  114. ^ Bellott, Brian J.; Ibers, James A. (December 2012). "Synthesis and Structure of the Rubidium Uranium Selenophosphate Rb 4 U 2 P 5 Se 17". Zeitschrift für anorganische und allgemeine Chemie. 638 (15): 2473–2476. doi:10.1002/zaac.201200316. ISSN 0044-2313.
  115. ^ Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1997-03-01). "Stabilization of U 5+ in Rb 4 U 4 P 4 Se 26 . An Actinide Compound with a Mixed Selenophosphate/Polyselenide Framework and Ion-Exchange Properties". Journal of the American Chemical Society. 119 (10): 2574–2575. doi:10.1021/ja963673j. ISSN 0002-7863.
  116. ^ Mesbah, Adel; Prakash, Jai; Beard, Jessica C.; Lebègue, Sébastien; Ibers, James A. (2018-11-30). "Synthesis and Crystal Structure of Cs 2 U 2 (P 2 Se 9 )(Se 2 ) 2". Zeitschrift für anorganische und allgemeine Chemie. 644 (22): 1480–1484. doi:10.1002/zaac.201800263. ISSN 0044-2313. S2CID 105028651.

Extra reading